Cf3so2ocf3
WebJul 12, 2024 · A convenient method for deoxyfluorination of arom. and aliph. carboxylic acids with CF3SO2OCF3 in the presence of a suitable base at room temp. has been developed. The reaction allows a straightforward access to a variety of acyl fluorides and proves that CF3SO2OCF3 is an effective deoxyfluorination reagent for carboxylic acids. WebDec 9, 2024 · A convenient method for deoxyfluorination of aromatic and aliphatic carboxylic acids with CF 3 SO 2 OCF 3 in the presence of a suitable base at room temperature has …
Cf3so2ocf3
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WebA convenient method for deoxyfluorination of aromatic and aliphatic carboxylic acids with CF3SO2OCF3 in the presence of a suitable base at room temperature has been … WebTrifluoromethyl trifluoromethanesulfonate, CF 3 SO 2 OCF 3, has been synthesised and its gas-phase structure determined from electron-diffraction data.This structural study was …
WebApr 28, 2016 · Silver-mediated direct trifluoromethoxylation of α-diazo esters and ketosteroid was disclosed. The reactions of alkyl α-diazo arylacetates with AgOCF3 or CF3SO2OCF3/AgF at -30 to 10 °C under a N2 atmosphere provided α-trifluoromethoxyl arylacetates in up to 90% yield, while alkyl α-diazo vinylacetates reacting with … WebJul 18, 2016 · ME Tuttolomondo, PE Anganaraz, EL Veretti, SA Hayes, DA Wann, HE Robertson, DWH Rankin and AB Altabef, Gas-phase structure and vibrational properties of trifluoromethyl trifluoromethanesulfonate,CF3SO2OCF3, Eur J Inorg Chem 10 (2007) 1381–1389. Crossref, ISI, Google Scholar; 33.
WebAug 1, 2015 · This reaction represents the first utilization of trifluoromethyl trifLUoromet hanesulfonate as a fluorination reagent and proves that CF3SO2OCF3 is an effective … WebPreparation of alkyl fluorides and carbonates via divergent dehydroxyfluorination and carbonation of alcohols with trifluoromethyl trifluoromethanesulfonate (CF3SO2OCF3) is described.
WebTrifluoromethyl trifluoromethanesulfonate (CF3SO2OCF3) No description defined. Statements. instance of. scholarly article. 0 references. title. Trifluoromethyl trifluoromethanesulfonate (CF3SO2OCF3) (English) 0 references. author name string. Yoshiro Kobayashi. series ordinal. 1.
WebSep 20, 2024 · Abstract A convenient method for deoxyfluorination of aromatic and aliphatic carboxylic acids with CF3SO2OCF3 in the presence of a suitable base at room temperature has been developed. The reaction... loch raven apartment homesWebMay 1, 1989 · I 1B NMR spectral analysis of the ethereal solution showed boron trifluoride (as its ether complex) as the only boron containing product. '3C and '9F NMR spectral analysis of the ethereal solution of the product mixture identified CF3SO20SO2CF3 and CF3SO2OCF3 with COF2 as the minor product. 19F NMR spectra also confirmed … indian scout 20 for saleWebSep 20, 2024 · CF3SO2OCF3 was demonstrated to be either a "F" or a "CO" reagent in the reactions by changing the base, allowing the selective construction of alkyl fluorides and … indian scout 249 for saleWebShelf-stable N-trifluoromethylthiophthalimide has been developed as an easily synthesized and efficient trifluoromethylthiolation reagent, and an array of valuable compounds were obtained employing this versatile SCF 3-reagent. 14 In 2000, Munavalli and coworkers reported the reaction of SCF 3-phthalimide with enamines, affording the α-trifluoromethyl … indian scout 450 camsWebMay 29, 1999 · The molecular structure of methyl trifluoromethanesulfonate (CH 3 OSO 2 CF 3, methyl triflate) was investigated by gas electron diffraction (GED) and … lochrasterplatine planen onlineWebApr 1, 2007 · Trifluoromethyl trifluoromethanesulfonate, CF3SO2OCF3, has been synthesised and its gas-phase structure determined from electron-diffraction data. This structural study was supported by HF, MP2 ... loch raven high school staffWebJan 1, 1980 · The mixture was stirred at reflux (sand bath temperature 175-80°) for about i0 hr. and the products condensable at -78° were collected. The volatile products were separated by repeated fractional condensation at -i00° (0.7239 g) and -196° (0.3929 g). Gas chromatographic separation (4', OV-210 on 80/100 chromosorb W) of the -196° cut ... indian scout 2020